4.8 Article

Strong Exciton-Photon Coupling in a Nanographene Filled Microcavity

Journal

NANO LETTERS
Volume 17, Issue 9, Pages 5521-5525

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.7b02211

Keywords

Micro cavity; nanographene; strong coupling; polaritons

Funding

  1. UK EPSRC [EP/M025330/1]
  2. Max Planck Society
  3. European Commission through the Graphene Flagship
  4. European Commission (project WASPS) [618078]
  5. Engineering and Physical Sciences Research Council [EP/M025330/1] Funding Source: researchfish
  6. EPSRC [EP/M025330/1] Funding Source: UKRI

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Dibenzo [hi,st] ovalene (DBOV)-a quasi-zero-dimensional nanographene-displays strong, narrow, and well-defined optical-absorption transitions at room temperature. On placing a DBOV-doped polymer film into an optical microcavity, we demonstrate strong coupling of the 0 -> 0' electronic transition to a confined cavity mode, with a coupling energy of 126 meV. Photoluminescence measurements indicate that the polariton population is distributed at energies approximately coincident with the emission of the DBOV, indicating a polariton population via an optical pumping mechanism.

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