Journal
ELECTROCHIMICA ACTA
Volume 178, Issue -, Pages 368-373Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.07.180
Keywords
Cobalt complex; molecular electrocatalyst; water reduction; hydrogen evolution
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Funding
- National Science Foundation of China [20971045, 21271073]
- Student Research Program (SRP) of South China University of Technology [B15-B7050170]
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A new molecular catalyst based on cobalt complex [LCoCl] (1) is formed by the reaction of N, N-dimethylethylenediamino-N, N-bis(2,4-dimethyl) phenol (H2L) with CoCl2 center dot 6H(2)O for electrolytic water reduction. To our knowledge 1 is by far the most active electrocatalyst for hydrogen generation from water with a turnover frequency (TOF) of 2744 mol of hydrogen per mole of catalyst per hour at an overpotential of -638 mV (pH 7.0). This is attributed to the ionic ligand, L-2, that coordinates strongly through two nitrogen atoms and two oxygen atoms to the cobalt center, leaving one Cl- ion in axial position and making the Cl- ion ionize in water. (C) 2015 Elsevier Ltd. All rights reserved.
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