Journal
ELECTROCHIMICA ACTA
Volume 178, Issue -, Pages 689-698Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.08.032
Keywords
Graphene/Mn3O4; Composite; Polyol process; Electrochemical; Supercapacitor
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Funding
- Teacher Research Foundation of Central South University [2014JSJJ023]
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Strongly coupled graphene/Mn3O4 (GM) composite has been synthesized via a polyol process together with a subsequent thermal annealing treatment. Mn3O4 nanoparticles with an average diameter of 20nm are uniformly adhered to a substrate of graphene sheets. The electrochemical properties of the composite for supercapacitor electrode in 1.0 M Na2SO4 aqueous solution were investigated by cyclic voltammetry (CV) and galvanostatic charge-discharge measurements. The GM composite exhibits more remarkable capacitance (270.6 F g(-1) at 0.2 A g(-1)) compared with the pure Mn3O4 (132.0 F g(-1) at 0.2 A g(-1)). After 1500 cycles, the retention rates of the composite and pure Mn3O4 at 2.0 A g(-1) are 91% and 71.4%, respectively. The good electrochemical performance of the GM composite could be attributed to the decreased agglomeration, enhanced conductivity, and the robust structure as a result of introducing graphene. These results render a new reasonable design of preparing nanomaterials with complex structures for supercapacitor applications. (C) 2015 Elsevier Ltd. All rights reserved.
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