Properties and electrochemical behaviors of AuPt alloys prepared by direct-current electrodeposition for lithium air batteries

AuPt catalyst has a prospective application in a lithium air battery because of its bi-function on catalyzing Oxygen Reduction Reaction (ORR) and Oxygen Evolution Reaction (OER). Electrodeposition is an in-situ convenient technology for catalyst preparation without chemical residue. In an acid electrolyte, AuPt alloy catalysts were electrodeposited on carbon paper. The effect of main salt concentration, electrodeposition time and current density were studied by deposit micromorphology observation, structure analyses and composition testing. Catalytic abilities of AuPt alloys were measured by cyclic voltammetry (CV) in an ionic liquid of EMI-TFSI/Li-TFSI [1-Ethyl-3-methylimidazolium-bis (trifluoromethanesulphonyl) imide/lithium-bis (trifluoromethanesulphonyl) imide]. The electrochemical behaviors of Au, Pt and AuPt deposits were also measured. An optimized direct-current electrodeposition process of getting high active AuPt catalyst is concluded, which is an aqueous solution containing 6.7 similar to 10 m mol.L-1 HAuCl4, 10 similar to 13.3 mmol.L-1 H2PtCl6 and 0.5 mol.L-1 H2SO4 as the electrolyte, current density of 20mA.cm(-2) and electrodeposition time of 8 similar to 34 s. The co-deposition of AuPt alloy is an irregular co-deposition controlled by diffusion, while gold atoms enter the platinum's crystal lattice in the structure of AuPt alloy. The increase of the concentration of H2PtCl6 in the electrolyte, the extension of the electrodeposition time or the raise of the current density can improve the content of Pt in the deposit. The clusters' diameters of AuPt catalysts decrease to 150 similar to 250 nm by adjusting current densities during electrodeposition. (C) 2014 Elsevier Ltd. All rights reserved.