Non-LTE line formation of Fe in late-type stars - IV. Modelling of the solar centre-to-limb variation in 3D

Our ability to model the shapes and strengths of iron lines in the solar spectrum is a critical test of the accuracy of the solar iron abundance, which sets the absolute zero-point of all stellar metallicities. We use an extensive 463-level Fe atom with new photoionization cross-sections for Fe I and quantum mechanical calculations of collisional excitation and charge transfer with neutral hydrogen; the latter effectively remove a free parameter that has hampered all previous line formation studies of Fe in non-local thermodynamic equilibrium (NLTE). For the first time, we use realistic 3D NLTE calculations of Fe for a quantitative comparison to solar observations. We confront our theoretical line profiles with observations taken at different viewing angles across the solar disc with the Swedish 1-m Solar Telescope. We find that 3D modelling well reproduces the observed centre-to-limb behaviour of spectral lines overall, but highlight aspects that may require further work, especially cross-sections for inelastic collisions with electrons. Our inferred solar iron abundance is log(epsilon(Fe)) = 7.48 +/- 0.04 dex.