4.6 Article

Biomolecule-assisted synthesis of porous PtPd alloyed nanoflowers supported on reduced graphene oxide with highly electrocatalytic performance for ethanol oxidation and oxygen reduction

Journal

ELECTROCHIMICA ACTA
Volume 160, Issue -, Pages 100-107

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.02.052

Keywords

Bimetallic alloy; Cytosine; Reduced graphene oxide; Ethanol oxidation reaction; Oxygen reduction reaction

Funding

  1. National Natural Science Foundation of China [21475118, 21175118, 21275130, 21275131]
  2. Zhejiang province university young academic leaders of academic climbing project [pd2013055]

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In this work, we have prepared porous PtPd alloyed nanoflowers uniformly supported on reduced graphene oxide by a simple and facile wet-chemical method, with the assistance of cytosine as a structure-directing agent. The products were mainly characterized by transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. The as-prepared nanocomposites displayed improved electrocatalytic performances toward ethanol oxidation in alkaline media and oxygen reduction in acidic media, which make it a promising electrocatalyst in fuel cells. (C) 2015 Elsevier Ltd. All rights reserved.

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