Journal
ELECTROCHIMICA ACTA
Volume 174, Issue -, Pages 456-463Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.06.031
Keywords
nickel-cobalt layered double hydroxides; hierarchical nanostructure; electrospinning; carbon nanofiber membrane; supercapacitors
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Funding
- National Natural Science Foundation of China [51125011, 51373037, 51433001]
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Hybrid nanomaterials with hierarchical structures have been considered as one kind of the most promising electrode materials for high-performance supercapacitors with high capacity and long cycle lifetime. In this work, multi-dimensional hybrid materials of nickel-cobalt layered double hydroxide (Ni-Co LDH) nanorods/nanosheets on carbon nanofibers (CNFs) were prepared by electrospinning technique combined with one-step solution co-deposition method. Carbon nanofiber membranes were obtained by electrospinning of polyacrylonitrile (PAN) followed by pre-oxidation and carbonization. The successful growth of Ni-Co LDH with different morphologies on CNF membrane by using two kinds of auxiliary agents reveals the simplicity and universality of this method. The uniform and immense growth of Ni-Co LDH on CNFs significantly improves its dispersion and distribution. Meanwhile the hierarchical structure of carbon nanofiber@nickel-cobalt layered double hydroxide nanorodsinanosheets (CNF@Ni-Co LDH NR/NS) hybrid membranes provide not only more active sites for electrochemical reaction but also more efficient pathways for electron transport. Galvanostatic charge-discharge measurements reveal high specific capacitances of 1378.2 F g(-1) and 1195.4 F g(-1) (based on Ni-Co LDH mass) at 1 A g(-1) for CNF@Ni-Co LDH NR and CNF@Ni-Co LDH NS hybrid membranes, respectively. Moreover, cycling stabilities for both hybrid membranes are significantly enhanced compared with those of Ni-Co LDH NR and NS powders. This facile method provides a new strategy for designs and applications of binary transition metal oxides/hydroxides deposited on various substrates for next-generation energy storage devices. (C) 2015 Elsevier Ltd. All rights reserved.
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