4.2 Article

Lead-rich carboxylate-substituted titanium-lead oxo clusters

Journal

MONATSHEFTE FUR CHEMIE
Volume 148, Issue 8, Pages 1371-1377

Publisher

SPRINGER WIEN
DOI: 10.1007/s00706-017-1972-2

Keywords

Metal oxo clusters; Lead compounds; Titanium compounds

Funding

  1. Austrian Science Fund (FWF)
  2. Fonds zur Forderung der wissenschaftlichen Forschung (FWF), Austria [P22536]
  3. X-ray center of Vienna University of Technology

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The carboxylate-substituted mixed-metal oxo clusters Pb6Ti6O9(acetate)(methacrylate)(17) and Pb4Ti8O10(OiPr)(18)(acetate)(2) contain a higher number of lead atoms in the cluster core than previously reported compounds. The metal atoms in both clusters are arranged in three layers of different composition, which are connected through oxygen, propionate and/or carboxylate bridges.

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