Journal
MOLECULES
Volume 22, Issue 5, Pages -Publisher
MDPI
DOI: 10.3390/molecules22050835
Keywords
alkenes; electrophilic fluorinating reagents; selenium catalysis; regioselectivity; stereoselectivity
Funding
- Sun Yat-Sen University
- One Thousand Youth Talents Program of China
- Natural Science Foundation of Guangdong Province [2014A030312018]
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A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination, syn- dichlorination, oxidative cyclization and asymmetric cyclization have been described.
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