Journal
ELECTROCHIMICA ACTA
Volume 186, Issue -, Pages 562-571Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.10.176
Keywords
Nickel cobalt sulfide; acetylene black; hollow microsphere; electrochemistry; asymmetric supercapacitor
Categories
Funding
- National Natural Science Foundation of China [21473258]
- Distinguished Young Scientists of Hunan Province [13JJ1004]
- Program for the New Century Excellent Talents in University [NCET-11-0513]
- Hunan Provincial Innovation Foundation for Postgraduate [CX2013B048]
- State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China
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High-rate acetylene black (AB) decorated NiCo2S4 hollow microsphere is prepared via a gas bubble soft template and hydrothermal methodology. Benefiting from the combined advantages of the AB with high conductivity and the nanopetals assembled NiCo2S4 with unique hollow micro-/nano-structures, abundant porosity and high conductivity, the as-obtained composites are found to exhibit high specific capacitances (768 F g(-1) at 2 A g(-1)) and remarkable rate capabilities (92.2, 80.1 and 70.3% of capacity retention rate at 20, 50 and 100 A g(-1)). The fabrication mechanism of the AB-NiCo2S4 composite is also proposed. Furthermore, an asymmetric supercapacitor is fabricated by using the AB-NiCo2S4 composite as a positive electrode and activated carbon as a negative electrode. Owing to the excellent electrochemical properties of the AB-(NiCoS4)-S-2 electrode, the asymmetric device delivers high energy density (24.7 Wh kg(-1)) at a power density of 428 W kg(-1) or high power density (17.12 kW kg(-1)) at a reasonable energy density of 7.1 Wh kg(-1), and exceptional cycling stability (105.6% of the initial capacity retention at 5 A g(-1) over 5000 cycles). These results above demonstrate the significance and great potential of mesoporous NiCo2S4 hollow microsphere-based composites in the development of high-performance energy-storage systems. (C) 2015 Elsevier Ltd. All rights reserved.
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