Journal
MOLECULES
Volume 22, Issue 3, Pages -Publisher
MDPI
DOI: 10.3390/molecules22030413
Keywords
electrochemical synthesis; single electron transfer; C,C cross-coupling
Funding
- JSPS KAKENHI [JP15H05847]
- Grants-in-Aid for Scientific Research [15K13691, 15H05847, 15H03843] Funding Source: KAKEN
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We have successfully developed a novel cathodic cross-coupling reaction of aryl halides with arenes. Utilization of the cathodic single electron transfer (SET) mechanism for activation of aryl halides enables the cross-coupling reaction to proceed without the need for any transition metal catalysts or single electron donors in a mild condition. The SET from a cathode to an aryl halide initiates a radical chain by giving an anion radical of the aryl halide. The following propagation cycle also consists entirely of anion radical intermediates.
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