Journal
MOLECULES
Volume 22, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/molecules22010109
Keywords
4-pyrones; diynones; water; transition-metal-free
Funding
- National Natural Science Foundation of China [21362002, 81260472]
- Guangxi Natural Science Foundation of China [2014GXNSFDA118007, 2016GXNSFEA380001]
- Project of Guangxi Department of Education [KY2014037]
- State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources [CMEMR2014-A02, CMEMR2012-A20]
- Fund of Guangxi Key Laboratory of Functional Phytochemicals Research and Utilization [FPRU2015-2]
- Guangxi's Medicine Talented Persons Small Highland Foundation [1306]
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Transition-metal-free synthesis of 4-pyrones via TfOH-promoted nucleophilic addition/cyclization of diynones and water has been developed. This transformation is simple, atom economical and environmentally benign, providing rapid and efficient access to substituted 4-pyrones.
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