Journal
MOLECULES
Volume 22, Issue 12, Pages -Publisher
MDPI
DOI: 10.3390/molecules22122201
Keywords
molecular switches; ferrocene; transition metal bis(dicarbollides)
Funding
- Russian Science Foundation [16-13-10331]
- Russian Science Foundation [16-13-10331] Funding Source: Russian Science Foundation
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Design of rotatory molecular switches based on extremely stable sandwich organometallic complexes ferrocene and bis(dicarbollide) complexes of transition metals is reviewed. The on-off switching in these systems can be controlled by various external stimuli such as change of the solution pH, interactions with coordinating species or redox reactions involving the central atom or substituents in the ligands.
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