Journal
DALTON TRANSACTIONS
Volume 48, Issue 1, Pages 99-106Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt03970d
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Funding
- Hydrocarbon Research Foundation
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The reactions of hydrogen cyanide, butyronitrile, cyclopropanecarbonitrile, pivalonitrile and benzonitrile with arsenic pentafluoride and antimony pentafluoride result in the formation of 1 : 1 Lewis adducts, while malononitrile yielded both 1 : 1 and 1 : 2 Lewis adducts. All adducts were isolated and characterized by multinuclear NMR and vibrational spectroscopy, and in most cases by their X-ray crystal structures.
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