Journal
MOLECULES
Volume 22, Issue 7, Pages -Publisher
MDPI
DOI: 10.3390/molecules22071149
Keywords
covalent organic framework; crystallization; dynamic covalent chemistry; hydrogen storage; methane storage; CO2 capture
Funding
- National Natural Science Foundation of China [21522105]
- 1000 Talent Plan (the Recruitment Program for Young Professionals)
- ShanghaiTech University Research Startup Fund
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Covalent organic frameworks (COFs) have emerged as a new class of crystalline porous materials prepared by integrating organic molecular building blocks into predetermined network structures entirely through strong covalent bonds. The consequently encountered crystallization problem has been conquered by dynamic covalent chemistry in syntheses and reticular chemistry in materials design. In this contribution, we have reviewed the progress in the crystallization of COF materials and their hydrogen, methane and carbon dioxide gas storage properties for clean energy applications.
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