Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 6, Issue 1, Pages 41-44Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00985f
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Funding
- CNRS, Normandie Universite
- INSA Rouen
- Labex Synorg [ANR-11-LABX-0029]
- Ministere de l'enseignement superieur et de la recherche
- University of Monastir
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This work describes an efficient -phosphorylation of a wide variety of N-aryl tertiary amines under mild conditions. It consists of a simple combination of amines (electron donors) with N-ethoxy-2-methylpyridinium tetrafluoroborate (electron acceptor) in the presence of P(v)-H compounds under visible light irradiation. Physical organic investigations support the formation of an electron-donor-acceptor complex (amine/pyridinium ion) as a key intermediate.
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