4.6 Article

A dynamic microporous magnet exhibiting room-temperature thermal hysteresis, variable magnetic ordering temperatures and highly selective adsorption for CO2

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 7, Issue 2, Pages 218-222

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc03356k

Keywords

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Funding

  1. National Natural Science Foundation of China [21303121, 21571140, 21531005]
  2. 973 Program [2014CB845601]
  3. Program for Innovative Research Team at University of Tianjin [TD13-5074]
  4. Open Fund of Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University, MOE)

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A dynamic microporous magnet shows reversible temperature-tuned single-crystal-to-single-crystal transformations by stepwise losing of coordinated and lattice water molecules, exhibiting an unusually observed room-temperature hysteresis loop, variablemagnetic ordering temperatures and high adsorption selectivity for CO2 over N-2.

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