4.6 Article

Ultra- robust carbon fibers for multi- media purification via solar- evaporation

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 2, Pages 586-593

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta08829b

Keywords

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Funding

  1. National Natural Science Foundation of China [51673209, 5161101025]
  2. Youth Innovation Promotion Association of Chinese Academy of Science [2014258]
  3. Ningbo Science and Technology Bureau [2014B81004, 2017C110034]

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Solar steam generation has been developed for purification of wastewater and seawater solely by virtue of sustainable solar energy. However, multi-media treatment, especially organic solvent purification, still remains challenging. Herein, the ultra-robust solar steam generator based on carbon fibers, modified by hydrothermal carbonization, is first fabricated for highly efficient purification of multi-media systems, including dyed organic solvent, oil-in-water emulsion and seawater. The modified carbon fibers show excellent mechanical strength (approximate to 4.77 GPa), good wettability, improved surface area and excellent light absorption (approximate to 93%) owing to the introduction of hierarchical carbon coating. The braiding fabrics can self-pump multi-media relying on the capillary forces among polar carbon fibers. Excellent production of clean water and organic solvent with high rejection of ions (<10 ppm salt ions), oil (approximate to 11.9 ppm oil) and dye (approximate to 99.99%) is demonstrated. After being corroded by dimethylacetamide (DMAc) and concentrated brine for 10 days, the tensile strength of carbon fiber filament is ultra-stable. The braiding carbon fiber fabrics can produce freshwater at a rate of 5.4 kg m(-2) per day from simulated Dead Seawater, enough to satisfy individual daily needs. Therefore, the carbon fiber-based materials have great application prospects for robust multi-media purification via highly efficient photothermal conversion.

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