Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 39, Issue 1, Pages 200-206Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc201808048
Keywords
trifluoromethanesulfonyl chloride; tetrahydrofuran; tetrahydropyran; visible light; alkoxyl-trifluoromethylation
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Funding
- National Natural Science Foundation of China [21722203, 21831002, 21801116, 21572096]
- Shenzhen Special Funds for the Development of Biomedicine, Internet, New Energy, and New Material Industries [JCYJ20170412152435366, JCYJ20170307105638498]
- Natural Science Foundation of Guangdong Province [2018A030310083]
- Shenzhen Nobel Prize Scientists Laboratory Project [C17213101]
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An efficient protocol for facile access to trifluoromethylated tetrahydrofuran and tetrahydropyran has been developed under visible light irradiation conditions via radical 1,2-alkoxyl-trifluoromethvlation of unactivated alkene. It features the use of readily commercially available and operatively simple trifluoromethanesulfonyl chloride as a trifluoromethyl radical source, thus making the protocol potentially appealing for practical preparation.
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