Journal
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
Volume 653, Issue 1, Pages 109-117Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/15421406.2017.1350040
Keywords
p-type dye-sensitized solar cells; double branched; hemicyanine; charge transfer
Funding
- Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea [20163010012310]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20163010012310] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Two double branched organic dyes (T1I and T2I) were synthesized, characterized, and employed as photosensitizers in p-type dye-sensitized solar cells (p-DSSC); we have compared with corresponding single branched dye (TC1) and reference dye P1. The absorbance of the dyes in solution was red shifted and the oxidation potential gradually decreased with increasing the donating ability. It was found that modification from single branched (TC1) to double branched (T1I and T2I) system resulted in increased photocurrent density leading to the higher photovoltaic performances. The charge transporting ability is increased with the introduction of double branching, as evidenced from electrochemical impedance analysis.
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