Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 17, Issue 4, Pages 845-850Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob03010c
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Funding
- Max-Planck Society, Germany
- DST, India [DST/INT/MPG/P-09/2016]
- CSIR [09/013(0650)/2016-EMR-I]
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A mild and efficient method is demonstrated for the transamidation of secondary amides with various amines including primary, secondary, cyclic and acyclic amines in the presence of tert-butyl nitrite. The reaction proceeds through the N-nitrosamide intermediate and provides the transamidation products in good to excellent yields at room temperature. Moreover, the developed methodology does not require any catalyst or additives.
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