Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 6, Pages 830-833Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07728b
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Funding
- NSFC [21602182]
- Sichuan Provincial Science and Technology Department [2016TD0014]
- Sichuan Provincial Education Department [16ZB0133]
- Longshan academic talent research supporting program of SVVUST [17LZX324, 18LZX305, 18LZXT02]
- Project of State Key Laboratory of Environment-friendly Energy Materials, SVVUST [17fksy0102]
- Postgraduate Innovation Fund Project by SVVUST [17ycx018]
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A one pot deboronation/cyclization of 9-amide-o-carboranes for the synthesis of nido-7,8-carborane fused oxazole by cooperation of Pd(OAc)(2), AgOAc and K2CO3 has been developed. A plausible mechanism involving an amide directed electrophilic palladation of the B-H bond and deboronation/cyclization process was proposed based on the successful isolation and structural characterization of the key deboronated intermediate.
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