Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 7, Pages 989-992Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07499b
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Funding
- SERB, India [ECR/2016/001272]
- IIT Madras
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AgSbF6-Catalyzed anti-Markovnikov addition of pinacolborane (HBpin) to terminal alkynes to produce the E-vinylboronates is reported. This efficient methodology is scalable, compatible with sterically and electronically diverse alkynes, and works at room temperature under solvent-free condition. The utility of this method is demonstrated in the facile synthesis of the clinically important (E)-2,4,3',5'-tetramethoxystilbene.
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