Journal
DALTON TRANSACTIONS
Volume 48, Issue 3, Pages 872-881Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt03743d
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Funding
- JSPS KAKENHI [18H04265, JP16H04119]
- JSPS
- PAN under the Research Cooperative Program Grant [AJ179063(29-9111-t11)]
- Toyota Physical and Chemical Research Institute
- Tonen General Sekiyu
- Grants-in-Aid for Scientific Research [18H04265] Funding Source: KAKEN
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The dihydrogenated porphycene cobalt(II) complex was synthesized and electrochemical experiments were carried out. The one-electron reduction of the complex proceeded at the central metal to afford the Co(I) species; in contrast, for the non-hydrogenated porphycene cobalt(II) complex, the one-electron reduction gave the ligand reduced radical anion species. The reactivity of the one-electron reduced species with alkyl halides showed clear differences between the complexes. Hydrogenation of the beta-position of the porphycene makes it possible to generate a central cobalt reduced species possessing a higher reactivity than the ligand reduced radical anion species.
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