Ultrathin flexible graphene films with high thermal conductivity and excellent EMI shielding performance using large-sized graphene oxide flakes

As the demand for wearable and foldable electronic devices increases rapidly, ultrathin and flexible thermal conducting films with exceptional electromagnetic interference (EMI) shielding effectiveness (SE) are greatly needed. Large-sized graphene oxide flakes and thermal treatment were employed to fabricate lightweight, flexible and highly conductive graphene films. Compared to graphene films made of smaller-sized flakes, the graphene film made of large-sized flakes possesses less defects and more conjugated domains, leading to higher electrical and higher thermal conductivities, as well as higher EMI SE. By compressing four-layer porous graphene films together, a 14 mm-thick graphene film (LG-4) was obtained, possessing EMI SE of 73.7 dB and the specific SE divided by thickness (SSE/t) of 25 680 dB cm(2) g(-1). The ultrahigh EMI shielding property of the LG-4 film originates from the excellent electrical conductivity (6740 S cm(-1)), as well as multi-layer structure composed of graphene laminates and insulated air pores. Moreover, the LG-4 film shows excellent flexibility and high thermal conductivity (803.1 W m(-1) K-1), indicating that the film is a promising candidate for lightweight, flexible thermal conducting film with exceptional EMI shielding performance.