4.6 Article

Interaction of water with methanesulfonic acid on Pt single crystal electrodes

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 50, Issue -, Pages 47-50

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2014.11.007

Keywords

Methanesulfonic acid; Platinum single crystal electrodes; Cyclic voltammetry; Anion adsorption

Funding

  1. scholarship Estudiantes sobresalientes de posgrado at the UNC
  2. COLCIENCIAS National Doctoral Scholarship [567]
  3. UNC [19030]
  4. Generalitat Valenciana (Feder) [PROMETEOII/2014/013]

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The electrochemical behavior of methanesulfonic acid on platinum single crystal electrode surfaces is investigated by cyclic voltammetry and infrared spectroscopy measurements. The results are compared with the voltammetric profiles of perchloric and trifluoromethanesulfonic acids. The differences are interpreted in terms of the effect of the anion on the structure of water. No adsorbed species are detected by infrared spectroscopy. (C) 2014 Elsevier B.V. All rights reserved.

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