4.7 Article

Modulation of emission properties of phosphine-sulfonate ligand containing copper complexes: playing with solvato-, thermo-, and mechanochromism

Journal

DALTON TRANSACTIONS
Volume 48, Issue 6, Pages 2128-2134

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt04502j

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Funding

  1. University of Rennes 1

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Modulations of various neutral phosphine containing copper(I) complexes exhibiting phosphorescence and TADF are easily achieved by solvent modification restricting intramolecular rotation or by modifying the L-X phosphine-sulfonate chelate. This concept is not limited to solvents as the addition of metallic salts also led to the formation of original well-defined photoluminescent K2CuLX3 and KCuL2X2 cuprate complexes.

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