Journal
DALTON TRANSACTIONS
Volume 48, Issue 6, Pages 1931-1935Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt04651d
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Funding
- National Natural Science Foundation of China [21871204, 21502132]
- 1000-Youth Talents Plan
- Jiangsu Specially-Appointed Professor Plan, PAPD
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201708]
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The reaction of terminal zinc hydrides with palladium(0) species afforded an unprecedented [eta(2)-Zn2Pd] trimetallic complex through the reductive elimination of H-2. In contrast, the reaction of zinc hydrides with a nickel(0) reagent gave sigma-Zn-H coordination complexes with no direct Zn-Zn bonding. Computational studies indicated that an oxidative addition/reductive elimination process at the palladium center might be responsible for the formation of a covalent Zn-Zn bond.
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