Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 246, Issue -, Pages 130-136Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2017.03.016
Keywords
Ultrathin nanosheets; Mesostructures; Ternary oxides; Lithium ion batteries
Categories
Funding
- NSFC [21271108, 21273118]
- China US Center for Environmental Remediation and Sustainable Development
- Tianjin Municipal Science and Technology Commission [11JCZDJC24800]
- MOE Innovation Team in China [IRT13022]
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Transition-metal oxides have been widely explored as the anode materials for lithium-ion batteries (LIBs) because of its low cost and high energy/power density. However, the electrode pulverization and capacity fading during cycling lead to poor cycling performance. Herein, ultrathin ZnCo2O4 nanosheets with desired mesoporosity and high surface area are prepared by a facile hydrothermal approach. Such ZnCo2O4 nanostructures show excellent lithium storage performance as anode materials for LIBs. At a current density of 1 A g(-1), the ultrathin ZnCo2O4 nanosheets present an initial specific capacity of 1251 mAh g(-1) and the specific capacity remains at 810 mAh g-1 even after 200 discharge charge cycles. (C) 2017 Elsevier Inc. All rights reserved.
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