Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 7, Pages 3228-3237Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta11426a
Keywords
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Funding
- National Natural Science Foundation of China [21576138, 51572127, 51872140]
- China-Israel Cooperative Program [2016YFE0129900]
- Natural Science Foundation of Jiangsu Province [BK20160828]
- PAPD of Jiangsu Province
- program for Science and Technology Innovative Research Team in Universities of Jiangsu Province, China
- [1501016B]
- [NCET-12-0629]
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Binder-free electrodes with core-shell structures have shown great potential in a variety of important energy storage systems. In order to endow the core-shell hierarchical structure with enhanced electrochemical properties, rationally designed and fabricated hierarchical structures with controllable morphology and great electrical conductivity are highly desired. In this work, a uniform dendritic SCo3O4@NiCo2S4 hierarchical structure grown on Ni foam was successfully designed and synthesized via sulfur-doping of Co3O4 (S-Co3O4) as the inner core with enhanced conductivity. The hierarchical electrode exhibited high areal capacity (10.9 mA h cm(-2) at a current density of 8 mA cm(-2)), a good rate performance (72.5% retention after increasing the current densities from 8 to 30 mA cm(-2)), and excellent cycling stability (97.3% retention after 5000 cycles). Moreover, a hybrid energy storage batterysupercapacitor device, constructed from a S-Co3O4@NiCo2S4 positive electrode and an active carbon (AC) negative electrode, showed high energy density and power density. Contributing to short ion diffusion, large electroactive sites and low contact resistance, our work not only demonstrates a promising electrode for energy storage battery-supercapacitor hybrid (BSH) devices, but also provides an attractive strategy for the design of electrode materials.
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