Journal
MICROCHIMICA ACTA
Volume 184, Issue 11, Pages 4537-4543Publisher
SPRINGER WIEN
DOI: 10.1007/s00604-017-2480-0
Keywords
Chemically modified electrode; Electrocatalytic oxidation; Nanohybrid; Thermal decomoposition; Electrochemical detection
Categories
Funding
- Islamic Azad University (Zanjan Branch)
- National Elites Foundation of Iran (INEF, Dr. Ashtiyani's Research grant) [1393-15/66597]
- Institute for Advanced Studies in Basic Sciences (IASBS) [G2016IASBS119]
Ask authors/readers for more resources
Gold nanoparticles (AuNP) were deposited on the surface of multiwalled carbon nanotubes (MWCNT) by in-situ thermal decomposition of gold acetate under solvent and reducing agent free conditions to obtain a nanohybrid of AuNP-MWCNT. A glassy carbon electrode (GCE) was then modified with the nanohybrid and used for amperometric determination of hydrazine. The modified GCE showed an improved electrocatalytic effect towards hydrazine oxidation at a working potential of about 0.30 V (vs Ag|AgCl, KClsat). The calibration plot for hydrazine is linear in two concentration ranges, viz. from 0.1-100 mu M and 0.2-1 mM. The respective sensitivities are 4.98 and 4.00 mu A mu M(-1)cm(-2), and the limit of detection (at S/N = 3) is about 30 nM.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available