Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 10, Pages 1430-1433Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc09361j
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Funding
- Natural Science Foundation of China (NSFC) [21776257]
- Natural Science Foundation of Zhejiang Province [LY17B030010]
- preferential Foundation of Zhejiang province postdoctoral research project
- Ministry of Science and Technology (MOST) [2016YFA0204100]
- National Natural Science Foundation of China [91845201, 21573254, 91545110]
- Youth Innovation Promotion Association, Chinese Academy of Sciences (CAS)
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A defective nanodiamond-graphene material (ND@G) exhibits superior catalytic activity in acetylene hydrochlorination with an acetylene conversion of 50%, selectivity to vinyl chloride of up to 99.5% at 220 degrees C, and a C2H2 gas hourly space velocity of 300 h(-1), which is the first example of a metal-free catalyst with comparable performance to that of the 0.25% Au/C catalyst.
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