Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 9, Pages 1213-1216Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc08198k
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Funding
- Thailand Research Fund
- Vidyasirimedhi Institute of Science and Technology [RSA6180031]
- Energy Policy and Planning Office (EPPO), Ministry of Energy, Thailand
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New insight into the influence of Li+, Na+, and K+ cations between adjacent layers of birnessite-type manganese oxides (MnOx) towards the intercalation/deintercalation charge storage mechanism as a neutral electrochemical capacitor (1 M Na2SO4) is demonstrated. These structural cations play amajor role in both the kinetic electron transfer in a faradaic redox reaction and the accessibility of the compensating electrolyte ions. Li-MnOx shows the highest Mn utilization of 51% followed by Na-MnOx (40%) and K-MnOx (31%), respectively.
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