Journal
ACS APPLIED ENERGY MATERIALS
Volume 2, Issue 1, Pages 192-195Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.8b01699
Keywords
CO2 reduction; electrocatalyst; gold; electronic structure; chemisorbing CO2
Funding
- National Key R&D Program of China [2017YFF0209805]
- National Natural Science Foundation of China [81771903, 51572062]
- Key Laboratory of Molecular Imaging Foundation (College of Heilongjiang Province)
- Natural Science Foundation of Heilongjiang Province of China [LC2016034, LC2013C26]
- Youth Science WU LIANDE Foundation of Harbin Medical University [WLD-QN1404, WLD-QN1119]
- Heilongjiang Postdoctoral Funds for Scientific Research Initiation [LBH-Q15090, LBH-Q16079]
- Fourth Hospital of Harbin Medical University Fund for Distinguished Young Scholars [HYDSYJQ201601]
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Inspired by the architectural feature of the natural enzyme of carbon monoxide dehydrogenase, cysteamine-capped Au nanoparticles (CA-Au NPs) are investigated with remarkable mass activity for CO2 reduction. CA-Au NPs exhibit exclusive CO selectivity, low onset over potential, and a 110-fold enhancement in mass activity compared with ligand-free Au NPs. Electronic structure and in situ spectroscopy analyses indicate that increased activity is due to the electronic effect derived from thiolate anchoring on the surface and chemisorbing CO2 and intermediates by terminal -NH2 functional groups. Our study provides the basis for fabricating effective catalysts for CO2 reduction.
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