Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 17, Issue 8, Pages 2103-2106Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02102c
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- Netherlands Organization for Scientific Research (NWO-CW, ECHO) [711.014.010]
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C-Terminal dipeptide isopropenyl esters were synthesised by a Cu(II)-mediated Chan-Lam-Evans enol esterification of peptide carboxylic acids and isoprenyl boroxine. These shelf stable peptide esters could be coupled stereoselectively with a variety of amino acid and dipeptide nucleophiles in high yield and purity in the presence of pyrazole/DBU as the catalyst.
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