4.7 Article

Enhanced photocatalytic activity of BiVO4 coupled with iron-based complexes for water oxidation under visible light irradiation

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 17, Pages 2529-2532

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc09807g

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Funding

  1. National Natural Science Foundation of China [21773096, 21572084]
  2. Fundamental Research Funds for the Central Universities [lzujbky-2018-k08]
  3. Natural Science Foundation of Gansu [17JR5RA186]

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[Fe-2(TPA)(2)(mu-O)Cl-2](2+) (TPA = tris(2-pyridylmethyl)amine) was investigated as a pre-catalyst, and greatly enhanced the photocatalytic water oxidation activity of BiVO4. An extremely high oxygen yield of 99.1% and apparent quantum yield of 44.3% were obtained in the BiVO4-NaIO3 photocatalytic water oxidation system.

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