Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 17, Pages 2517-2520Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc09713e
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Funding
- Advanced Low Carbon Technology-Specially Promoted Research for Innovative Next Generation Batteries Program (ALCA-SPRING) of Japan Science and Technology Agency (JST)
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The atomic structure of a spinel-type MgCo2O4 nanoparticle was investigated by the reverse Monte Carlo modelling using X-ray and neutron total scattering data. It is found that Mg at an octahedral site induces a significant structural distortion, while Mg at a tetrahedral site is considered to move easily to a vacant site. Based on the results, we propose a guideline for the development of a better positive electrode material for a Mg rechargeable battery.
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