Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 17, Issue 8, Pages 2162-2168Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob03189d
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Funding
- National Natural Sciences Foundation of China [21672032, 21802016]
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A concise and catalyst-free aryltrifluoromethylative cyclization of unactivated alkenes has been developed herein. The use of PhICF3Cl as a powerful trifluoromethylating agent allows easy transformations. A set of trifluoroethylated carbocycles and aza-hereocycles were efficiently synthesized in good yield and selectivity. A broad substrate scope, mild reaction conditions, and easy operation would make this method well-suited for applications.
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