Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 17, Issue 7, Pages 1731-1735Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02224k
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Funding
- JSPS KAKENHI [JP17H05051, JP16H06384]
- Platform Project for Supporting Drug Discovery and Life Science Research from the Japan Agency for Medical Research and Development (AMED)
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A palladium-catalyzed intramolecular carboborylation of 1,3-diene has been developed for the synthesis of iminoindolines with a quaternary carbon centre. This method was applied to a substrate bearing several functional groups to afford a complex iminoindoline, which was subsequently converted into an ABCD ring model compound of communesins via an intramolecular Friedel-Crafts-type reaction.
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