Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 15, Pages 2154-2157Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc09304k
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Funding
- Australian Research Council [DP160103244]
- UNSW Faculty of Engineering Start-up grant
- UNSW Faculty Fellowship
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A non-persistent radical precursor, N-hydroxyphthalimide (NHPI), is reported as a low-cost, high-potential organic cathode in a binary electrolyte for a semi-aqueous redox battery. A highly reversible NHPI-phthalimide N-oxyl (PINO) radical redox couple at +1.30 V-NHE is demonstrated, providing a 1.15 V rechargeable battery with an attractive >85% voltage efficiency when coupled with anthraquinone-2-sulfonic acid (AQS).
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