4.7 Article

Selective oxidation of methane to methanol with H2O2 over an Fe-MFI zeolite catalyst using sulfolane solvent

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 20, Pages 2896-2899

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc10026h

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Funding

  1. Education, Culture, Sports, Science and Technology of Japan (MEXT) [16H04566]
  2. JST PRESTO, Japan [JPMJPR15S8]
  3. Grants-in-Aid for Scientific Research [16H04566] Funding Source: KAKEN

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The effect of reaction conditions for direct oxidation of methane to methanol over Fe- MFI zeolite with H2O2 has been investigated. Sulfolane has been proved to be an efficient solvent for liquid- phase methane oxidation. A sulfolane/water mixture with an appropriate proportion led to an extremely high methanol production with a high selectivity.

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