4.6 Article

NO oxidative activity of mesoporous LaMnO3 and LaCoO3 perovskite nanoparticles by facile molten-salt synthesis

Journal

NEW JOURNAL OF CHEMISTRY
Volume 43, Issue 7, Pages 2974-2980

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj04590a

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Funding

  1. National Natural Science Foundation of China [21666016]

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LaMnO3 and LaCoO3 perovskite nanoparticles have sprung up as the platinum group-metal (PGM)-free catalysts of NO oxidation to reduce NOX in the exhaust. In this paper, we present mesoporous LaMnO3 and LaCoO3 with rhombohedral structures prepared by a facile molten-salt synthesis method. LaMnO3 and LaCoO3 achieved NO oxidation performance with the highest NO conversions of 85% and 94% at 300 degrees C, which may be improved by K and Na introduced via flux.

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