Journal
GREEN CHEMISTRY
Volume 21, Issue 4, Pages 770-774Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc03529f
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Funding
- National Key Research and Development Program of China [2018YFB0605801, 2017YFA0403103]
- National Natural Science Foundation of China [21603235]
- Chinese Academy of Sciences [QYZDY-SSW-SLH013]
- Recruitment Program of Global Youth Experts of China
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Herein, we demonstrate that quantum-sized Ru dot decorated ultra-thin anatase TiO2 nanosheets with exposed (001) facets could exhibit highly efficient catalytic activity during the conversion of levulinic acid to -valerolactone at room temperature. The support effect has been largely attributed to the high energy of TiO2 (001) which can lead to a stronger interaction between the support and the metal. The surface of Ru/TiO2-n contains more Ru(0) and results in higher activity and selectivity.
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