Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 9, Issue 4, Pages 947-956Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cy02173b
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Funding
- Youth Foundation of Wuhan Institute of Technology [K201514]
- Natural Science Foundation of Hubei Province, China [2015CFB166]
- Program for Element Strategy Initiative for Catalysts & Batteries (ESICB), Platform for Technology and Industry by Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [26289305]
- Grants-in-Aid for Scientific Research [26289305] Funding Source: KAKEN
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Supported Pt-Sn bimetallic catalysts directly reduced by H-2 (DR method) are highly active for the dehydrogenation of n-butane, while the catalysts calcined in air, followed by H-2 reduction (CR method), are totally inactive regardless of the calcination temperature and Sn/Pt ratio. The present work investigated the detailed bulk and surface structural properties of the catalysts with various characterization techniques. The results suggest that both DR and CR methods led to the formation of bulk Pt-Sn alloys (e.g. Pt3Sn and PtSn). However, calcination before reduction significantly changed the catalyst surface properties. The SnO2 layer was located on the surface of the Pt-Sn alloys and/or Pt nanoparticles when the catalysts were prepared with the CR method. In contrast, the DR method induced more surface exposed Pt atoms from the Pt3Sn alloy, which played an important role in the superior catalytic behaviors for n-butane dehydrogenation.
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