Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 166, Issue 4, Pages C91-C100Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0921904jes
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Funding
- National Natural Science Foundation of China [51871049, 51622106]
- National Key R&D Program of China [2017YFB0702303]
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The growth of metastable pits on sputtered nanocrystalline stainless steel (NCss) was simulated by a cellular automata technology. Pit morphologies, passive film breakdown, and the metal cation concentration inside the metastable pit during its growth were analyzed. The combined effects of passive film breakdown and repassivation hindered metastable pit growth on the NCss, even though their isolated effects may vary significantly. The calculated values of the critical pitting temperature are shown to be statistically distributed because of the difficulty of passive film breakdown, repassivation, and the metastable/stable pitting transition. (C) 2019 The Electrochemical Society.
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