Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 19, Pages 2833-2836Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00007k
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Funding
- Department of Science and Technology, India [SERB-ECR/2017/001477]
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A visible light-induced vicinal diazidation of various alkenes using stable sulfonium bis(acetoxy)iodate(i) and sodium azide as a radical precursor is described. The trimethylsulfonium [bis(azido)iodate(i)] species, intrinsically generated in situ, demonstrated unprecedented reactivity toward C?C bond-promoting selective azidation under photochemical conditions without any photoredox or metal catalyst. The visible-light stimulated diazidation reaction provides a convenient and straightforward approach to highly prevalent vicinal nitrogen scaffolds of myriad therapeutic importance.
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