Journal
CHEMICAL SCIENCE
Volume 10, Issue 11, Pages 3237-3241Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc05096a
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Funding
- Pfizer
- Engineering and Physical Sciences Research Council [EP/N509711/1]
- Cancer Research UK [C5255/A16466]
- Agency for Science, Technology and Research (A*STAR, Singapore)
- UCB
- EPSRC [1809880] Funding Source: UKRI
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Herein, we report the radiosynthesis of F-18-difluoromethylarenes via the assembly of three components, a boron reagent, ethyl bromofluoroacetate, and cyclotron-produced non-carrier added [F-18] fluoride. The two key steps are a copper-catalysed cross-coupling reaction, and a Mn-mediated F-18-fluorodecarboxylation.
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