Journal
GREEN CHEMISTRY
Volume 21, Issue 6, Pages 1467-1471Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc03876g
Keywords
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Funding
- National Institutes of Health [R01GM121660]
- National Science Foundation of China [NSFC-21672035]
- Camille and Henry Dreyfus Foundation
- California State University, Fresno
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The combination of two easily handled, highly acidic liquid HF complex reagents, DMPU-12HF and KHSO4-13HF, generated a highly acidic fluorination system that facilitated exclusive Markovnikov addition of HF to widely functionalized alkynes, including alkyne tethered drugs, or allenes to produce gem-difluorides with high atom economy, and with an easy workup.
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