Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 20, Pages 2928-2931Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00621d
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Funding
- National Science Centre NCN, Poland [2016/21/B/ST5/03088]
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The first example of CO2 diphosphination is described. Reactions of unsymmetrical diphosphanes with CE2 (E = O, S) catalyzed by BPh3 insert a CE2 molecule into the P-P bond with formation of the products of the general formula R2P-E-C(?E)-PR2. The obtained CO2 adducts arise from synergistic interaction of diphosphane and borane with CO2 molecule.
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