Negative thermal expansion in high pressure layered perovskite Ca2GeO4

We report the high pressure synthesis of a layered perovskite Ca2GeO4 which is found to have the Ruddlesden-Popper structure with I4(1)/acd symmetry. Consonant with our recent predictions [Ablitt et al., npj Comput. Mater., 2017, 3, 44], the phase displays pronounced uniaxial negative thermal expansion over a large temperature range. Negative thermal expansion that persists over a large temperature range is very unusual in the perovskite structure, and its occurrence in this instance can be understood to arise due to both soft lattice vibrations associated with a phase competition and the unusually compliant nature of this structure, which effectively couples thermal expansion in the layer plane to lattice contractions perpendicular to the layering direction via a corkscrew mechanism.